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Posted on October 26, 2021 by  &  with 1 Comment

New Record of 25.8% Conversion Efficiency of Perovskite Solar Cells

New Record of 25.8% Conversion Efficiency of Perovskite Solar Cells
A research team, led by Professor Sang Il Seok in the School of Energy and Chemical Engineering at UNIST has set a new efficiency record for a perovskite solar cell (PSC) at 25.8% by forming an interlayer between electron-transporting and perovskite layers to minimize interfacial defects, contributing to the decrease in the power conversion efficiencies. The new record, according to the research team, is the world's highest power conversion efficiency (PCE) reported so far. Besides, the record, certified by National Renewable Energy Laboratory (NREL), is also the highest confirmed conversion efficiency of 25.5%.
In perovskite solar cells, the interfaces between the perovskite and charge-transporting layers contain high concentrations of defects, specifically deep-level defects, which substantially reduce the power conversion efficiency of the devices, noted the research team. Efforts have been made to reduce these interfacial defects have focused mainly on surface passivation. Yet, passivating the perovskite surface that interfaces with the electron-transporting layer has been difficult, because the surface-treatment agents on the electron-transporting layer may dissolve while coating the perovskite thin film. For further information see the IDTechEx report on Perovskite Photovoltaics 2018-2028.
"Alternatively, interfacial defects may not be a concern if a coherent interface could be formed between the electron-transporting and perovskite layers," said the research team.
In this study, the research team reported the formation of an interlayer between a SnO2 electron-transporting layer and a halide perovskite light-absorbing layer, achieved by coupling Cl-bonded SnO2 with a Cl-containing perovskite precursor.
This interlayer, according to the research team, has atomically coherent features, which enhance charge extraction and transport from the perovskite layer, and fewer interfacial defects. "The existence of such a coherent interlayer allowed us to fabricate perovskite solar cells with a power conversion efficiency of 25.8% under standard illumination," the team said, adding that unencapsulated devices maintained about 90% of their initial efficiency even after continuous light exposure for 500 hours. They anticipate that such findings provide guidelines for designing defect-minimizing interfaces between metal halide perovskites and electron-transporting layers.
The findings of this research have been published in the October 2021 issue of Nature.
Source: UNIST
Top image: Pixabay
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